Pacman saves important configuration files when removing certain applications and names them with the extension: .pacsave. To prevent the creation of these backup files use the -n option:
# pacman -Rn package_name
Note: Pacman will not remove configurations that the application itself creates (for example "dotfiles" in the home folder).
Basically, pacman will not remove those configuration files in Home folder you will have to remove them manually. Those packages created by the application have no impact on a system after you remove the package so it won't do any harm. That is just how it works.
Usually all the configurations files created by the apps are in ~/config folder. You can just type in terminal rm -r and drag & drop folders to terminal and click Enter or whatever works best for you.