I used bcache only in a writethrough configuration, and IIRC even then bcache doesn't like at all if the cache device vanishes while the machine is running. Expect the bcache device to stall completely if that happens.
I haven't tried to remove the cache device while the machine is powered down, so I can't say anything about that. I do think though that bcache is still pretty touchy, so I'd recommend that you try that with a VM or a physical test machine first.
To safely remove the cache device, you can detach the cache set from the bcache device:
echo <cache-set-uuid> > /sys/block/bcache0/bcache/detach
To determine the necessary cache set UUID, look in /sys/fs/bcache/:
host ~ # ll /sys/fs/bcache/
total 0
drwxr-xr-x 7 root root 0 Feb 19 00:11 eb99feda-fac7-43dc-b89d-18765e9febb6
--w------- 1 root root 4096 Feb 19 00:11 register
--w------- 1 root root 4096 Feb 7 07:17 register_quiet
So for example in this case, run:
echo eb99feda-fac7-43dc-b89d-18765e9febb6 > /sys/block/bcache0/bcache/detach
The state file should say no cache after that:
host ~ # cat /sys/block/bcache0/bcache/state
no cache