This doesn't indicate the mail was sent using PHP mail() function, as it's just one example of applications sending mail through Sendmail. It could be anything that utilizes Postfix's local submissions. From Postfix Architecture Overview: How Postfix receives mail:
Local submissions are received with the Postfix sendmail(1)
compatibility command, and are queued in the maildrop queue by the
privileged postdrop(1) command. This arrangement even works while the
Postfix mail system is not running. The local pickup(8) server picks
up local submissions, enforces some sanity checks to protect Postfix,
and gives the sender, recipients and message content to the cleanup(8)
server.
The pickup is aware of the user that used the postdrop.
postfix/pickup[4771]: A70248414D5: uid=0 from=<root>
The cleanup adds a unique message ID and a received header based on this information.
postfix/cleanup[4776]: cleanup_header_callback:
'Received: by example.com (Postfix, from userid 0)
??id A70248414D5; Sun, 26 Apr 2020 16:49:01 +0200 (CEST)'
postfix/cleanup[4776]: A70248414D5: message-id=<[email protected]>
The from literally means the user the message is from.
The userid 0 indicates it's from the root.